Dynamic Buffer Capacities in Redox Systems

The buffer capacity concept is extended on dynamic redox systems, realized according to titrimetric mode, where changes in pH are accompanied by changes in potential E values; it is the basic novelty of this paper. Two examples of monotonic course of the related curves of potential E vs. and pH vs. Φ relationships were considered. The systems were modeled according to GATES/GEB principles.

Author(s):

Anna Maria Michalowska-Kaczmarczyk, Aneta Sporna-Kucab, Tadeusz Michalowski

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